You've got the "minus" ("-") formats (DVD-R, DVD-RW) and the "plus" ("+") formats (DVD+R, DVD+RW), then there's the older DVD-RAM format that's harder to find these days. All of these are for data, of course -- all but the newest DVD video players will choke on those, in the same way early CD players choked on CD-R discs.
A DVD-R is a write-once format: once you've burned the data onto that DVD platter, the disk is forever frozen with that information. Add the "W" to that, and you'll find that DVD-RW can be erased or rewritten up to a thousand times. Seems kinda weird, but if you can do so, DVD-RW obviously has significant advantages over DVD-R. DVD-RAM was even more flexible, however, since it let you erase and rewrite sections of an existing DVD, something that you cannot do with DVD-RW.
Moving to the plus side is where things get a bit confusing, because DVD+RW came before DVD+R. The plus formats have the same data storage capacity as the minus formats (4.7GB), but DVD+RW offers faster writing, better internal linking (a technical obscurity you don't have to worry about), and support for drag-and-drop desktop files, which makes it easy to compose the contents of a disk. DVD+R is a write-once format intended to be more compatible with more DVD players, though at this point it seems to be about even with DVD-R, which remains the most compatible computer-burned DVD format.