will a neutured male cat still try to mate with a cat in heat?

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my cat is in heat and today i saw a cat she plays with a lot (who we thought was a girl) try to mate with her.. but im sure he must be neutured as i cant see any, you know, but this stray cat who isnt neutured tried to mate with her and she was growling and hissing..

it doesnt make sense,or will the female reject the male at first and then let him mate?
x
 
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