Do u think chemistry between a guy and a girl is mostly a 'first sight/meeting thing?

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Or can it start happening once you get to know each other more?
 
Usually when I like a guy I just met it's because I think he's good looking and it has nothing to do with his personality. But I think real chemistry comes after you get to know them a little and something between you clicks.
 
You need to know someone to have chemistry with them, there is no 'first sight/meeting thing'
 
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