no, acer 5332 are ENTRY level computers and do not come configured with blueray. Your video solution is not good enough to resolve it AND your screen is not good enough to resolve blueray.
Even a cheap $80 set top box blueray player gives better pic quality than a $3000 alienware laptop. Set top boxes use hardware decoding. Computers use software decoding.
You can buy a blueray player and install it yourself. You will also need decoding software but most players will give it to you free. But you will not really notice a difference between that and dvd on THAT machine. A laptop with a better screen and vid solution plays blueray pretty well. (but again, not as well as a set top box)