What program can I use to take screen shots of DVDs?

You can use the PrintScreen command

this button on your keyboard

you can stop your dvd which part you can take snap shoot you can press the button of PrintScreen and open MSPaint and paste it and save in Jpg format.
 
Press the PrtScr button on your keyboard. Open MSPaint. Press CTRL+V.

Try Irfanview - http://www.irfanview.com
 
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